N.M.R. orbital shifts of 125Te in solids, dependence on ionicity and local structure
نویسندگان
چکیده
2014 The orbital chemical shift of N.M.R., which measures the weight of non-s states in the chemical bond, can be related directly to the ionicity for tellurium compounds. In a molecular picture of the solid neglecting d states, the shift is a parabolic function of the number of p-electrons in the valence band. This number depends simply on the ionicity for tellurium bonds and can be modified by change in the local symmetry, especially by amorphization. JOURNAL DE PHYSIQUELETTRES ~ TOME 38, 15 JANVIER 1977,
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